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lithium oxide : ウィキペディア英語版
lithium oxide

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Lithium oxide (O) or lithia is an inorganic chemical compound. Lithium oxide is formed along with small amounts of lithium peroxide when lithium metal is burned in the air and combines with oxygen:
:4Li + → 2.
Pure can be produced by the thermal decomposition of lithium peroxide, , at 450 °C〔
:2 → 2 +
==Structure==
In the solid state lithium oxide adopts an antifluorite structure which is related to the , fluorite structure with Li cations substituted for fluoride anions and oxide anions substituted for calcium cations.
The ground state gas phase molecule is linear with a bond length consistent with strong ionic bonding.〔Wells A.F. (1984) ''Structural Inorganic Chemistry'' 5th edition Oxford Science Publications ISBN 0-19-855370-6〕〔A spectroscopic determination of the bond length of the LiOLi molecule: Strong ionic bonding, D. Bellert, W. H. Breckenridge, J. Chem. Phys. 114, 2871 (2001); 〕 VSEPR theory would predict a bent shape similar to .

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